Steel Microstructure and Compressive Strength in Mortar When an Electrochemical Chloride Extraction is Applied

Steel Microstructure and Compressive Strength in Mortar When an Electrochemical Chloride Extraction is Applied

Loading document ...
Page
of
Loading page ...

Author(s)

Author(s): Citlalli Gaona-Tiburcio, S. Rodríguez, L. Hernández, O. Guarneros, A. Cárdenas

Download Full PDF Read Complete Article

647 1108 18-27 Volume 2 - May 2013

Abstract

The focus of this paper is to examine and review how applications of Electrochemical Chloride Extraction (ECE) affect the mortar mechanical properties. The mortar specimens were prepared with water/cement (w/c) ratio of 0.5 and contaminated with 5% of NaCl by mass of cement. A clean steel rod was centrally embedded in each specimen. The electrochemical treatments were based on different electrical current densities of 1, 3, 6 and 9 A/m2 that were applied for 15 days. The state of corrosion was monitored before, during and after applying ECE regularly for two weeks. Selected samples from the cover zone of the untreated and treated specimens were taken to assess their chloride profiles. Despite being a slight change in the microstructure at the surface of the steel rod when this technique was applied (high current densities), the results of the compressive strength on mortars were not affected by ECE.

Keywords

Corrosion, Chloride, Mortar, Microstructure, Compressive Strength

References

  1. P. Claude Aı̈tcin, Cements of yesterday and today: Concrete of tomorrow. Cem. Concr. Res.30, 2000 (9) 1349–1359
  2. K. Yong Ann, H. Won Song, Chloride threshold level for corrosion of steel in concrete. Corros. Sci. 49, 2007 (11) 4113–4133
  3. J. Gulikers, Development of a galvanic monitoring probe to improve service life prediction of reinforced concrete structures with respect to reinforcement corrosion. Constr. Build. Mater. 11, 1997 (3) 143–148
  4. V. Saraswathy H. Won Song, Electrochemical studies on the corrosion performance of steel embedded in activated fly ash blended concrete. Electrochim. Acta 51, 2006 (22), 4601–4611
  5. G.S. Duffó, S.B. Farina C.M. Giordano, Characterization of solid embeddable reference electrodes for corrosion monitoring in reinforced concrete structures. Electrochim. Acta, 2009, 54 (3) 1010-1020
  6. A. Muntean, M. Böhm, J. Kropp, Chemical Engineering Science, 2011, 66 (3) 538–547
  7. M. Grantham, Diagnosis, inspection, testing and repair of reinforced concrete structures. Advanced Concrete Technology Set, 2003 Volume 2, 1-54
  8. M. Miranda, E. Otero, J.A. González, Limitations and advantages of electrochemical chloride removal in corroded reinforced concrete structures. Cem. Concr. Res. 37, 2007 (4) 596–603
  9. G. Fajardo, G. Escadeillas, G. Arliguie, Electrochemical chloride extraction (ECE) from steel-reinforced concrete specimens contaminated by “artificial” sea-water. Corros. Sci. 48, 2006 (1) 110-125
  10. J.C Orellan, G Escadeillas, G Arliguie, Electrochemical chloride extraction: efficiency and side effects . Cem. Concr. Res. 34, 2004 (2) 227-234
  11. P. Garcés, M.J. Sánchez de Rojas, M.A. Climent, Effect of the reinforcement bar arrangement on the efficiency of electrochemical chloride removal technique applied to reinforced concrete structures. Corros. Sci. 48, 2006 (3) 531-545
  12. Nzeribe M. Ihekwaba, Brian B. Hope, Mechanical properties of anodic and cathodic regions of ECE treated concrete. Cem. Concr. Res. 26, 1996 (5) 771-780
  13. ASTM C192/C192M-07. Standard practice for making and curing concrete test specimens in the laboratory, Book of standards, 2007 Vol. 04.02
  14. ASTM C39/C39M-05e1. Standard test method for compressive strength of cylindrical concrete specimens book of standards,2005 vol. 04.02
  15. M. Stern, A.L. Geary, J. Electrochemical Soc. 1957, 104 (56)
  16. ASTM C-876-91. Standard test method for half-cell potentials of uncoated reinforcing steel in concrete; 1999
  17. MF. Asaro, AT. Gaynor, S.Hettiarachi, Electrochemical chloride removal and protection of concrete bridge components Strategic highway research program report SHRP–S/FR-90– 002. Washington (DC): NRC; 1990
  18. M. Sánchez , M.C. Alonso, Electrochemical chloride removal in reinforced concrete structures: Improvement of effectiveness by simultaneous migration of calcium nitrite . Construction and Building Materials, 2011, 25 (2) 873–878
  19. G.E. Abdelaziz , A.M.K. Abdelalim, Y.A. Fawzy, Evaluation of the short and long-term efficiencies of electro-chemical chloride extraction Cem. Concr. Res. 2009, 39 (8) 727–732
  20. C. Andrade, I. Martinez, Castellote, “Efficiency control electrochemical repair techniques”. Concrete repair, Rehabilitation and Retrofitting II, South Africa, 2008, p. 24-26
  21. B. Elsener, U. Angst, Mechanism of electrochemical chloride removal . Corros. Sci. 2007, 49 (12) 4504-4522
  22. W.K. Green, S.B. Lyon, J.D. Scantlebury, Electrochemical changes in chloride-contaminated reinforced concrete following cathodic polarisation. Corros. Sci. 1993, 35 (5) 1627–1631
  23. N.R. Buenfeld J.P. Broomfield, International Conference on Corrosion Protection of steel in Concrete, Sheffield, UK, (1994) 1438-1451
  24. N.M. Ihekwaba, B.B. Hope, C.M. Hansson, Pull-out and bond degradation of steel rebars in ECE concrete. Cem. Concr. Res. 1996, 26 ( 2) 267-282
  25. J.B. Miller, Structural aspects on high powered electrochemical treatment of reinforced concrete, in: Proccedings of the International Conference on Corrosion and Protection of Steel in Concrete, 24-28 July, Sheffield, UK, 1994
  26. T.D. Marcotte, C.M. Hansson, B.B. Hope, The effect of the electrochemical chloride extraction treatment on steel-reinforced mortar Part I: Electrochemical measurements . Cem. Concr. Res. 1999, 29 (10) 1555-1560
  27. M. Siegwart, F. Lyness, J. McFarland, Change of pore size in concrete due to electrochemical chloride extraction and possible implications for the migration of ions. Cem. Concr. Res. 2003, 33 (8) 1211-1221
  28. Kalliopi K Aligizaki, Mario R de Rooij, Digby D Macdonald. Analysis of iron oxides accumulating at the interface between aggregates and cement paste. Cem. Concr. Res. 2000, 30 (12) 1941-1945
  29. S. Rodriguez, J. Miranda , C. Gaona, L. Narváez, L. Hernández, Port. Electrochim. Acta 2010, 28 (3) 153-164. Estado de la Corrosión en Probetas de Acero Embebidas en Mortero después de una Extracción Electroquímica de Cloruros.. ISSN 0872-1904

Cite this Article:

International Journal of Sciences is Open Access Journal.
This article is licensed under a Creative Commons Attribution 4.0 International (CC BY 4.0) License.
Author(s) retain the copyrights of this article, though, publication rights are with Alkhaer Publications.

Search Articles

Issue June 2023

Volume 12, June 2023


Table of Contents



World-wide Delivery is FREE

Share this Issue with Friends:


Submit your Paper